Jangro ntrl Probiotic Washroom Cleaner Sachet

ntrl Probiotic Washroom Cleaner (water soluble
paper sachet)
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Issue date: 07/02/2024 Revision date: 02/06/2025 Supersedes version of: 10/02/2025 Version: 1.02
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name : ntrl Probiotic Washroom Cleaner (water soluble paper sachet)
UFI : 8N6V-A16Y-000J-J7MU
Product code : BF120
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Main use category : Professional use
Use of the substance/mixture : Biological product for complete washroom cleaning.
Uses advised against
Restrictions on use : Not for direct application to food stuffs, Not for oral consumption
1.3. Details of the supplier of the safety data sheet
Jangro Ltd
Jangro Ltd (UK): 1A Parklands, 3rd Floor, Lostock, Bolton, BL6 4SD, UK
Jangro Ltd (Europe): 6-9 Trinity Street, Dublin 2, D02 EY47, IRELAND
T UK: +44 (0) 1204 795 955 Dublin: 01 617 7911
enquiries@jangrohq.net
1.4. Emergency telephone number
Emergency number : +44 (0) 1204 795 955 (8am to 5pm)
Country/Area Organisation/Company Address Emergency number Comment
Ireland National Poisons Information Centre PO Box 1297 +353 1 809 2566
Beaumont Hospital Beaumont Road (Healthcare professionals-
9 Dublin 24/7)
+353 1 809 2166 (public,
8am – 10pm, 7/7)
United Kingdom NHS 111/NHS 24/NHS Direct 111 or call a doctor
0845 4647
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Serious eye damage/eye irritation, Category 2 H319
Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :
GHS07
02/06/2025 (Revision date) GB – en 1/11
ntrl Probiotic Washroom Cleaner (water soluble paper sachet)
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Signal word (CLP) : Warning
Hazard statements (CLP) : H319 – Causes serious eye irritation.
Precautionary statements (CLP) : P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+P313 – If eye irritation persists: Get medical advice/attention.
2.3. Other hazards
This product does not contain substances at ≥0.1% that meet the PBT criteria of UK REACH regulation, annex XIII
This product does not contain substances at ≥0.1% that meet the vPvB criteria of UK REACH regulation, annex XIII
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission
Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Name Product identifier % Classification according to
Regulation (EC) No. 1272/2008
[CLP]
Sodium Carbonate CAS-No.: 497-19-8 ≥ 25 – < 50 Eye Irrit. 2, H319 EC-No.: 207-838-8 REACH-no: 01-2119485498- 19-XXXX Citric acid CAS-No.: 5949-29-1 ≥ 10 – < 20 Eye Irrit. 2, H319 EC-No.: 201-069-1 STOT SE 3, H335 EC Index-No.: 607-750-00-3 REACH-no: 01-2119457026- 42-XXXX C08-10 Alkyl glucoside CAS-No.: 68515-73-1 ≥ 1 – < 5 Eye Dam. 1, H318 EC-No.: 500-220-1 REACH-no: 01-2119488530- 36-XXXX Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : To our knowledge, the product does not present any particular risk, under normal conditions of use. If the person feels unwell : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Wash skin with plenty of water. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth out with water. Call a POISON CENTER/doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects : Causes serious eye irritation. Symptoms/effects after inhalation : May cause slight irritation. Symptoms/effects after skin contact : May cause slight irritation to the skin. Symptoms/effects after eye contact : May cause eye irritation. Symptoms/effects after ingestion : May cause irritation to the digestive tract. 02/06/2025 (Revision date) GB - en 2/11 ntrl Probiotic Washroom Cleaner (water soluble paper sachet) Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Dry powder. Foam. 5.2. Special hazards arising from the substance or mixture Fire hazard : Not flammable. Explosion hazard : Product is not explosive. Reactivity in case of fire : Product is not explosive. Hazardous decomposition products in case of fire : Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Oxides of the following substances: Carbon. 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Always wash hands after handling the product. For non-emergency personnel Protective equipment : Wear recommended personal protective equipment. Avoid contact with skin. Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Measures in case of dust release : Ventilate area. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid direct discharge into drains. 6.3. Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Wash the spillage site with large amounts of water. Other information : Avoid disposing into drainage systems and into the environment. Dispose of in accordance with local regulations. 6.4. Reference to other sections No additional information available SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Avoid creating or spreading dust. Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Hygiene measures : Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Does not require any specific or particular technical measures. 02/06/2025 (Revision date) GB - en 3/11 ntrl Probiotic Washroom Cleaner (water soluble paper sachet) Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 Storage conditions : Store in a dry place. Store in a closed container. Keep cool. Incompatible products : Strong acids. Strong alkalis. 7.3. Specific end use(s) Washroom dosing product. SECTION 8: Exposure controls/personal protection 8.1. Control parameters DNEL and PNEC Citric acid (5949-29-1) PNEC (Water) PNEC aqua (freshwater) 0.44 mg/l PNEC aqua (marine water) 0.044 mg/l PNEC (Sediment) PNEC sediment (freshwater) 34.6 mg/kg dwt PNEC sediment (marine water) 3.46 mg/kg dwt PNEC (Soil) PNEC soil 33.1 mg/kg dwt PNEC (STP) PNEC sewage treatment plant 1000 mg/l Sodium Carbonate (497-19-8) DNEL/DMEL (Workers) Long-term - local effects, inhalation 10 mg/m³ DNEL/DMEL (General population) Acute - local effects, inhalation 10 mg/m³ C08-10 Alkyl glucoside (68515-73-1) DNEL/DMEL (Workers) Long-term - systemic effects, dermal 595000 mg/kg bodyweight/day Long-term - systemic effects, inhalation 420 mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 35.7 mg/kg bodyweight/day Long-term - systemic effects, inhalation 124 mg/m³ Long-term - systemic effects, dermal 357000 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 0.176 mg/l PNEC aqua (marine water) 0.0176 mg/l PNEC aqua (intermittent, freshwater) 0.27 mg/l PNEC (Sediment) PNEC sediment (freshwater) 1516 mg/kg dwt PNEC sediment (marine water) 0.152 mg/kg dwt 02/06/2025 (Revision date) GB - en 4/11 ntrl Probiotic Washroom Cleaner (water soluble paper sachet) Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 C08-10 Alkyl glucoside (68515-73-1) PNEC (Soil) PNEC soil 0.654 mg/kg dwt PNEC (Oral) PNEC oral (secondary poisoning) 111.11 mg/kg food PNEC (STP) PNEC sewage treatment plant 560 mg/l β-Alanine, N-(2-carboxyethyl)-, N-coco alkyl derivs., disodium salts (90170-43-7) DNEL/DMEL (Workers) Long-term - systemic effects, dermal 2.67 mg/kg bodyweight/day Long-term - systemic effects, inhalation 980 mg/m³ PNEC (Water) PNEC aqua (freshwater) 0.1 mg/l PNEC aqua (marine water) 0.01 mg/l PNEC aqua (intermittent, freshwater) 0.1 mg/l PNEC (STP) PNEC sewage treatment plant 0.3 mg/l 8.2. Exposure controls Personal protection equipment Personal protective equipment: Always wash hands after handling the product. Wear recommended personal protective equipment. Personal protective equipment symbol(s): Eye and face protection Eye protection: Acu aizsarglīdzekļi nav lietojami, jo produkts atrodas ūdenī šķīstošā paciņā. Always wash hands after handling the product Skin protection Skin and body protection: No special clothing/skin protection equipment is recommended under normal conditions of use Hand protection: In case of repeated or prolonged contact wear gloves. Always wash hands after handling the product Respiratory protection Respiratory protection: No respiratory protection needed under normal use conditions Thermal hazards Thermal hazard protection: Not required. 02/06/2025 (Revision date) GB - en 5/11 ntrl Probiotic Washroom Cleaner (water soluble paper sachet) Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : Pale Pink. Appearance : Fine Powder. Odour : Pleasant. Odour threshold : Not available Melting point : Not available Freezing point : Not available Boiling point : Not available Flammability : Not flammable Lower explosion limit : Not applicable Upper explosion limit : Not applicable Flash point : Not applicable Auto-ignition temperature : Not applicable Decomposition temperature : Not available pH : 8 – 8 saturated aqueous solution pH solution : Not available Viscosity, kinematic : Not applicable Solubility : Soluble in water. Partition coefficient n-octanol/water (Log Kow) : Not available Vapour pressure : Not available Vapour pressure at 50°C : Not available Density : 1.05 – 1.1 @ 20ºC Relative density : Not available Relative vapour density at 20°C : Not applicable Particle size : Not available 9.2. Other information Other safety characteristics VOC content : NO VOC Content SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability No additional information available 10.3. Possibility of hazardous reactions No additional information available 10.4. Conditions to avoid No additional information available 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products No additional information available 02/06/2025 (Revision date) GB - en 6/11 ntrl Probiotic Washroom Cleaner (water soluble paper sachet) Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified Citric acid (5949-29-1) LD50 oral 5400 mg/kg bodyweight Animal: mouse, Guideline: OECD Guideline 401 (Acute Oral Toxicity), Remarks on results: other:, 95% CL: 4500 - 6400 LD50 dermal rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity)
Sodium Carbonate (497-19-8)
LD50 oral rat 2800 mg/kg bodyweight Animal: rat
LD50 dermal rabbit > 2000 mg/kg bodyweight Animal: rabbit, Guideline: other:
C08-10 Alkyl glucoside (68515-73-1)
LD50 oral rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 423 (Acute Oral toxicity
– Acute Toxic Class Method), Guideline: EU Method B.1 tris (Acute Oral Toxicity – Acute
Toxic Class Method)
LD50 dermal rabbit > 2000 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity)
Skin corrosion/irritation : Not classified
pH: 8 – 8 saturated aqueous solution
Sodium Carbonate (497-19-8)
pH ≈ 11.6 Concentration: (≈)0,1 other:
Serious eye damage/irritation : Causes serious eye irritation.
pH: 8 – 8 saturated aqueous solution
Sodium Carbonate (497-19-8)
pH ≈ 11.6 Concentration: (≈)0,1 other:
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
Citric acid (5949-29-1)
STOT-single exposure May cause respiratory irritation.
STOT-repeated exposure : Not classified
Citric acid (5949-29-1)
LOAEL (oral, rat, 90 days) 8000 mg/kg bodyweight Animal: rat
NOAEL (oral, rat, 90 days) 4000 mg/kg bodyweight Animal: rat
C08-10 Alkyl glucoside (68515-73-1)
NOAEL (oral, rat, 90 days) 100 mg/kg bodyweight Animal: rat, Guideline: EU Method B.26 (Sub-Chronic Oral Toxicity
Test: Repeated Dose 90-Day Oral Toxicity Study in Rodents)
Aspiration hazard : Not classified
11.2. Information on other hazards
No additional information available
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ntrl Probiotic Washroom Cleaner (water soluble paper sachet)
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
SECTION 12: Ecological information
12.1. Toxicity
Hazardous to the aquatic environment, short–term : Not classified
(acute)
Hazardous to the aquatic environment, long–term : Not classified
(chronic)
Sodium Carbonate (497-19-8)
LC50 – Fish [1] 300 mg/l Test organisms (species): Lepomis macrochirus
EC50 – Crustacea [1] 200 – 227 mg/l Test organisms (species): Ceriodaphnia sp.
EC50 – Crustacea [2] 200 – 227 mg/l Test organisms (species): Ceriodaphnia sp.
C08-10 Alkyl glucoside (68515-73-1)
LC50 – Fish [1] 100.81 mg/l Test organisms (species): Danio rerio (previous name: Brachydanio rerio)
LC50 – Fish [2] 170 mg/l Test organisms (species): Danio rerio (previous name: Brachydanio rerio)
EC50 – Crustacea [1] > 100 mg/l Test organisms (species): Daphnia magna
EC50 72h – Algae [1] 27.22 mg/l Test organisms (species): Desmodesmus subspicatus (previous name:
Scenedesmus subspicatus)
EC50 72h – Algae [2] 37 mg/l Test organisms (species): Desmodesmus subspicatus (previous name:
Scenedesmus subspicatus)
12.2. Persistence and degradability
ntrl Probiotic Washroom Cleaner (water soluble paper sachet?
Persistence and degradability Not rapidly degradable
Citric acid (5949-29-1)
Persistence and degradability Readily biodegradable.
Sodium Carbonate (497-19-8)
Persistence and degradability The product is inorganic so can not be biodegradable, however it is expected to degrade
or disassociate.
C08-10 Alkyl glucoside (68515-73-1)
Persistence and degradability Readily biodegradable.
12.3. Bioaccumulative potential
Citric acid (5949-29-1)
Bioaccumulative potential Not potentially bioaccumulable.
Sodium Carbonate (497-19-8)
Bioaccumulative potential Not potentially bioaccumulable.
C08-10 Alkyl glucoside (68515-73-1)
Bioaccumulative potential Not potentially bioaccumulable.
12.4. Mobility in soil
ntrl Probiotic Washroom Cleaner (water soluble paper sachet?
Additional information Soluble in water
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ntrl Probiotic Washroom Cleaner (water soluble paper sachet)
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
12.5. Results of PBT and vPvB assessment
ntrl Probiotic Washroom Cleaner (water soluble paper sachet?
This product does not contain substances at ≥0.1% that meet the PBT criteria of UK REACH regulation, annex XIII
This product does not contain substances at ≥0.1% that meet the vPvB criteria of UK REACH regulation, annex XIII
12.6. Endocrine disrupting properties
No additional information available
12.7. Other adverse effects
Other adverse effects : No adverse affects known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
No additional information available
SECTION 14: Transport information
In accordance with ADR / IMDG / IATA / ADN / RID
ADR IMDG IATA ADN RID
14.1. UN number or ID number
Not applicable Not applicable Not applicable Not applicable Not applicable
14.2. UN proper shipping name
Not applicable Not applicable Not applicable Not applicable Not applicable
14.3. Transport hazard class(es)
Not applicable Not applicable Not applicable Not applicable Not applicable
14.4. Packing group
Not applicable Not applicable Not applicable Not applicable Not applicable
14.5. Environmental hazards
Not applicable Not applicable Not applicable Not applicable Not applicable
No supplementary information available
14.6. Special precautions for user
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
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ntrl Probiotic Washroom Cleaner (water soluble paper sachet)
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
14.7. Maritime transport in bulk according to IMO instruments
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU-Regulations
REACH Annex XVII (Restriction List)
Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (2024/590)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 2024/590 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items
Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
VOC Directive (2004/42)
VOC content : NO VOC Content
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain
substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
National regulations
According REACH Regulation 1907/2006 as retained in UK law by UK REACH SI 2019 No. 758 as amended
UK HSE EH40 workplace exposure limits
15.2. Chemical safety assessment
No additional information available
SECTION 16: Other information
Full text of H- and EUH-statements:
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
The classification complies with : ATP 12
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ntrl Probiotic Washroom Cleaner (water soluble paper sachet)
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
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