Jangro ntrl Probiotic Toilet Cleaner – 5L

ntrl Probiotic Toilet Cleaner 5L
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Issue date: 14/10/2020 Revision date: 02/06/2025 Supersedes version of: 10/02/2025 Version: 1.04
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Product name : ntrl Probiotic Toilet Cleaner 5L
Product code : BF021-5
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Main use category : Professional use
Use of the substance/mixture : Toilet and Urinal Cleaner
Uses advised against
Restrictions on use : Not for oral consumption, Not for direct application to food stuffs.
1.3. Details of the supplier of the safety data sheet
Jangro Ltd
Jangro Ltd (UK): 1A Parklands, 3rd Floor, Lostock, Bolton, BL6 4SD, UK
Jangro Ltd (Europe): 6-9 Trinity Street, Dublin 2, D02 EY47, IRELAND
T UK: +44 (0) 1204 795 955 Dublin: 01 617 7911
enquiries@jangrohq.net
1.4. Emergency telephone number
Emergency number : +44 (0) 1204 795 955 (8am to 5pm)
Country/Area Organisation/Company Address Emergency number Comment
Ireland National Poisons Information Centre PO Box 1297 +353 1 809 2566
Beaumont Hospital Beaumont Road (Healthcare professionals-
9 Dublin 24/7)
+353 1 809 2166 (public,
8am – 10pm, 7/7)
United Kingdom NHS 111/NHS 24/NHS Direct 111 or call a doctor
0845 4647
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Adverse physicochemical, human health and environmental effects
To our knowledge, the product does not present any particular risk, under normal conditions of use. Presents no particular risk to the environment.
2.2. Label elements
According to EC directives or the corresponding national regulations there is no labelling obligation for this product.
No labelling applicable
2.3. Other hazards
This mixture is not considered to be persistent, bioaccumulating and toxic (PBT)
This mixture is not considered to be persistent, bioaccumulating and toxic (PVB)
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
02/06/2025 (Revision date) GB – en 1/11
ntrl Probiotic Toilet Cleaner 5L
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission
Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Name Product identifier % Classification according to
Regulation (EC) No. 1272/2008
[CLP]
Alcohols, C12-14(even numbered), ethoxylated, CAS-No.: 68891-38-3 ≥ 3 – < 5 Skin Irrit. 2, H315 sulfates, sodium salts (< 2.5EO) EC-No.: 500-234-8 Eye Dam. 1, H318 REACH-no: 01-2119488639- Aquatic Chronic 3, H412 16-XXXX 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N- CAS-No.: 147170-44-3 ≥ 1 – < 3 Eye Dam. 1, H318 dimethyl-, N-C8-18 acyl derivs., inner salts EC-No.: 931-296-8 Aquatic Chronic 3, H412 REACH-no: 01-2119489410- 39-XXXX Specific concentration limits: Name Product identifier Specific concentration limits (%) Alcohols, C12-14(even numbered), ethoxylated, CAS-No.: 68891-38-3 (5 ≤ C < 9.9) Eye Irrit. 2; H319 sulfates, sodium salts (< 2.5EO) EC-No.: 500-234-8 (10 ≤ C < 100) Eye Dam. 1; H318 REACH-no: 01-2119488639- 16-XXXX 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N- CAS-No.: 147170-44-3 (4 ≤ C < 9.9) Eye Irrit. 2; H319 dimethyl-, N-C8-18 acyl derivs., inner salts EC-No.: 931-296-8 (10 ≤ C < 100) Eye Dam. 1; H318 REACH-no: 01-2119489410- 39-XXXX Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : To our knowledge, the product does not present any particular risk, under normal conditions of use. Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Wash skin with plenty of water. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth out with water. Call a POISON CENTER/doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects : To our knowledge, the product does not present any particular risk, under normal conditions of use. Symptoms/effects after inhalation : To our knowledge, the product does not present any particular risk, under normal conditions of use. Symptoms/effects after skin contact : To our knowledge, the product does not present any particular risk, under normal conditions of use. Symptoms/effects after eye contact : May cause slight irritation to eyes. Symptoms/effects after ingestion : May cause irritation to the digestive tract. 02/06/2025 (Revision date) GB - en 2/11 ntrl Probiotic Toilet Cleaner 5L Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Dry powder. Foam. 5.2. Special hazards arising from the substance or mixture Fire hazard : Not flammable. Explosion hazard : Product is not explosive. Reactivity in case of fire : Product is not explosive. Hazardous decomposition products in case of fire : On heating irritating fumes to eyes or skin may be produced. 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Always wash hands after handling the product. For non-emergency personnel Protective equipment : No special requirement . Avoid contact with skin. Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Measures in case of dust release : Not applicable (aqueous liquid). For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions No special environmental precautions required. 6.3. Methods and material for containment and cleaning up For containment : Collect spillage. Stop leak without risks if possible. Methods for cleaning up : Wash the spillage site with large amounts of water. Other information : Small amount of unwanted product may be flushed with water to sewer. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Not expected to present a significant hazard under anticipated conditions of normal use. Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Hygiene measures : Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Does not require any specific or particular technical measures. Storage conditions : Store in a dry place. Store in a closed container. Keep cool. Incompatible products : Strong acids. Strong alkalis. 02/06/2025 (Revision date) GB - en 3/11 ntrl Probiotic Toilet Cleaner 5L Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 7.3. Specific end use(s) Toilet & Urinal Cleaning Liquid. SECTION 8: Exposure controls/personal protection 8.1. Control parameters National occupational exposure and biological limit values ntrl Probiotic Toilet Cleaner 5L ( ) United Kingdom - Occupational Exposure Limits Remark Contains no substances with occupational work exposure limits. DNEL and PNEC 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-C8-18 acyl derivs., inner salts (147170-44-3) DNEL/DMEL (Workers) Long-term - systemic effects, dermal 12.5 mg/kg bodyweight/day Long-term - systemic effects, inhalation 44 mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 7.5 mg/kg bodyweight/day Long-term - systemic effects, inhalation 13.04 mg/m³ Long-term - systemic effects, dermal 7.5 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 0.0135 mg/l PNEC aqua (marine water) 0.00135 mg/l PNEC (Sediment) PNEC sediment (freshwater) 11.1 mg/kg dwt PNEC sediment (marine water) 1.11 mg/kg dwt PNEC (Soil) PNEC soil 0.85 mg/kg dwt PNEC (STP) PNEC sewage treatment plant 3000 mg/l Alcohols, C12-14(even numbered), ethoxylated, sulfates, sodium salts (< 2.5EO) (68891-38-3) DNEL/DMEL (Workers) Long-term - systemic effects, dermal 2750 mg/kg bodyweight/day Long-term - local effects, dermal 132 µg/cm² Long-term - systemic effects, inhalation 175 mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 15 mg/kg bodyweight/day Long-term - systemic effects, inhalation 52 mg/m³ Long-term - systemic effects, dermal 1650 mg/kg bodyweight/day Long-term - local effects, dermal 79 µg/cm² 02/06/2025 (Revision date) GB - en 4/11 ntrl Probiotic Toilet Cleaner 5L Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 Alcohols, C12-14(even numbered), ethoxylated, sulfates, sodium salts (< 2.5EO) (68891-38-3) PNEC (Water) PNEC aqua (freshwater) 0.24 mg/l PNEC aqua (marine water) 0.024 mg/l PNEC aqua (intermittent, freshwater) 0.071 mg/l PNEC (Sediment) PNEC sediment (freshwater) 0.9168 mg/kg dwt PNEC sediment (marine water) 0.0917 mg/kg dwt PNEC (Soil) PNEC soil 7.5 mg/kg dwt PNEC (STP) PNEC sewage treatment plant 10 g/l 8.2. Exposure controls Appropriate engineering controls Appropriate engineering controls: No special requirement. Personal protection equipment Personal protective equipment: Eye protection not applicable. Avoid contact with eyes. Personal protective equipment symbol(s): Eye and face protection Eye protection: Eye protection not applicable. Avoid contact with eyes Skin protection Skin and body protection: No special requirement Hand protection: In case of repeated or prolonged contact wear gloves. Always wash hands after handling the product Hand protection Type Material Permeation Thickness (mm) Penetration Standard Disposable gloves, Type Nitrile rubber (NBR) 1 (> 10 minutes) EN ISO 374
C
Reusable gloves, Type A Nitrile rubber (NBR) 2 (> 30 minutes) >0.38mm EN ISO 374
Other skin protection
Materials for protective clothing:
Not applicable.
Respiratory protection
Respiratory protection:
No respiratory protection needed under normal use conditions
02/06/2025 (Revision date) GB – en 5/11
ntrl Probiotic Toilet Cleaner 5L
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Thermal hazards
Thermal hazard protection:
Not required.
Environmental exposure controls
Environmental exposure controls:
This product does not present any particular risk for the environment.
Consumer exposure controls:
The substance is not classified for human health hazards or for environment effects and it is not PBT or vPvB so that no exposure assessment or
risk characterisation is required. For tasks where the intervention of workers is required, the substance must be handled in accordance with good
industrial hygiene and safety procedures.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Green.
Appearance : Viscous liquid.
Odour : Pleasant.
Odour threshold : Not available
Melting point : Not applicable
Freezing point : Not available
Boiling point : Not available
Flammability : Not flammable
Lower explosion limit : Not available
Upper explosion limit : Not available
Flash point : Not available
Auto-ignition temperature : Not available
Decomposition temperature : Not available
pH : 6 – 7
Viscosity, kinematic : Not available
Solubility : Soluble in water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Vapour pressure : Not available
Vapour pressure at 50°C : Not available
Density : 1.03 – 1.04 @ 20ºC
Relative density : Not available
Relative vapour density at 20°C : Not available
Particle characteristics : Not applicable
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
02/06/2025 (Revision date) GB – en 6/11
ntrl Probiotic Toilet Cleaner 5L
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Alcohols, C12-14(even numbered), ethoxylated, sulfates, sodium salts (< 2.5EO) (68891-38-3) LD50 oral rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral
Toxicity)
LD50 dermal rat ≥ 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity), Remarks on results: other:
Skin corrosion/irritation : Not classified
pH: 6 – 7
Serious eye damage/irritation : Not classified
pH: 6 – 7
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Alcohols, C12-14(even numbered), ethoxylated, sulfates, sodium salts (< 2.5EO) (68891-38-3) LOAEL (oral, rat, 90 days) 25 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 408 (Repeated Dose 90- Day Oral Toxicity Study in Rodents), Remarks on results: other: NOAEL (oral, rat, 90 days) > 225 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 408 (Repeated Dose 90-
Day Oral Toxicity Study in Rodents), Remarks on results: other:
Aspiration hazard : Not classified
11.2. Information on other hazards
No additional information available
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
Hazardous to the aquatic environment, short–term : Not classified
(acute)
Hazardous to the aquatic environment, long–term : Not classified
(chronic)
1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-C8-18 acyl derivs., inner salts (147170-44-3)
LC50 – Fish [1] 1.11 mg/l Test organisms (species): Pimephales promelas
EC50 – Crustacea [1] 6.5 mg/l Test organisms (species): Daphnia magna
EC50 72h – Algae [1] 1.5 mg/l Fresh water
02/06/2025 (Revision date) GB – en 7/11
ntrl Probiotic Toilet Cleaner 5L
Safety Data Sheet
According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Alcohols, C12-14(even numbered), ethoxylated, sulfates, sodium salts (< 2.5EO) (68891-38-3) LC50 - Fish [1] 7.1 mg/l Test organisms (species): Danio rerio (previous name: Brachydanio rerio) EC50 - Crustacea [1] 7.4 mg/l Test organisms (species): Daphnia magna EC50 72h - Algae [1] 27.7 mg/l Test organisms (species): Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) NOEC (chronic) 0.27 mg/l Test organisms (species): Daphnia magna Duration: '21 d' NOEC chronic fish 0.14 mg/l Test organisms (species): Oncorhynchus mykiss (previous name: Salmo gairdneri) Duration: '28 d' 12.2. Persistence and degradability ntrl Probiotic Toilet Cleaner 5L Persistence and degradability Readily biodegradable. 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-C8-18 acyl derivs., inner salts (147170-44-3) Persistence and degradability Readily biodegradable. Alcohols, C12-14(even numbered), ethoxylated, sulfates, sodium salts (< 2.5EO) (68891-38-3) Persistence and degradability Readily biodegradable. 12.3. Bioaccumulative potential ntrl Probiotic Toilet Cleaner 5L Bioaccumulative potential The product is miscible in water and readily biodegradable in both water and soil. Accumulation is not expected. 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-C8-18 acyl derivs., inner salts (147170-44-3) Bioaccumulative potential Not expected to Bioaccumulate. Alcohols, C12-14(even numbered), ethoxylated, sulfates, sodium salts (< 2.5EO) (68891-38-3) Bioaccumulative potential Not expected to Bioaccumulate. 12.4. Mobility in soil ntrl Probiotic Toilet Cleaner 5L Additional information Soluble in water 12.5. Results of PBT and vPvB assessment ntrl Probiotic Toilet Cleaner 5L This mixture is not considered to be persistent, bioaccumulating and toxic (PBT) This mixture is not considered to be persistent, bioaccumulating and toxic (PVB) 12.6. Endocrine disrupting properties Adverse effects on the environment caused by : The substance/mixture does not contain components considered to have endocrine endocrine disrupting properties disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7. Other adverse effects Other adverse effects : No adverse affects known. 02/06/2025 (Revision date) GB - en 8/11 ntrl Probiotic Toilet Cleaner 5L Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions. SECTION 14: Transport information In accordance with ADR / IMDG / IATA / ADN / RID ADR IMDG IATA ADN RID 14.1. UN number or ID number Not applicable Not applicable Not applicable Not applicable Not applicable 14.2. UN proper shipping name Not applicable Not applicable Not applicable Not applicable Not applicable 14.3. Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable Not applicable 14.4. Packing group Not applicable Not applicable Not applicable Not applicable Not applicable 14.5. Environmental hazards Not applicable Not applicable Not applicable Not applicable Not applicable No supplementary information available 14.6. Special precautions for user Overland transport Not applicable Transport by sea Not applicable Air transport Not applicable Inland waterway transport Not applicable Rail transport Not applicable 14.7. Maritime transport in bulk according to IMO instruments Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations REACH Annex XVII (Restriction List) Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions) REACH Annex XIV (Authorisation List) Contains no substance(s) listed on REACH Annex XIV (Authorisation List) 02/06/2025 (Revision date) GB - en 9/11 ntrl Probiotic Toilet Cleaner 5L Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 REACH Candidate List (SVHC) Contains no substance(s) listed on the REACH Candidate List PIC Regulation (Prior Informed Consent) Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals) POP Regulation (Persistent Organic Pollutants) Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants) Ozone Regulation (2024/590) Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 2024/590 on substances that deplete the ozone layer) Council Regulation (EC) for the control of dual-use items Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items Explosives Precursors Regulation (2019/1148) Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors) Drug Precursors Regulation (273/2004) Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances) National regulations UK HSE EH40 workplace exposure limits Regulation (EC) 1907/2006 - REACH (UK amended) 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Abbreviations and acronyms: ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR European Agreement concerning the International Carriage of Dangerous Goods by Road ATE Acute Toxicity Estimate BCF Bioconcentration factor BLV Biological limit value BOD Biochemical oxygen demand (BOD) COD Chemical oxygen demand (COD) DMEL Derived Minimal Effect level DNEL Derived-No Effect Level EC-No. European Community number EC50 Median effective concentration EN European Standard IARC International Agency for Research on Cancer IATA International Air Transport Association IMDG International Maritime Dangerous Goods LC50 Median lethal concentration LD50 Median lethal dose LOAEL Lowest Observed Adverse Effect Level NOAEC No-Observed Adverse Effect Concentration 02/06/2025 (Revision date) GB - en 10/11 ntrl Probiotic Toilet Cleaner 5L Safety Data Sheet According to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 Abbreviations and acronyms: NOAEL No-Observed Adverse Effect Level NOEC No-Observed Effect Concentration OECD Organisation for Economic Co-operation and Development OEL Occupational Exposure Limit PBT Persistent Bioaccumulative Toxic PNEC Predicted No-Effect Concentration RID Regulations concerning the International Carriage of Dangerous Goods by Rail SDS Safety Data Sheet STP Sewage treatment plant ThOD Theoretical oxygen demand (ThOD) TLM Median Tolerance Limit VOC Volatile Organic Compounds CAS-No. Chemical Abstract Service number N.O.S. Not Otherwise Specified vPvB Very Persistent and Very Bioaccumulative ED Endocrine disruptor Full text of H- and EUH-statements: Aquatic Chronic 3 Hazardous to the aquatic environment – Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. Safety Data Sheet (SDS), EU This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 02/06/2025 (Revision date) GB - en 11/11